9-(Biphenyl-4-yloxycarbonyl)-10-methylacridinium trifluoromethanesulfonate
نویسندگان
چکیده
منابع مشابه
9-(Biphenyl-4-yloxycarbonyl)-10-methylacridinium trifluoromethanesulfonate
In the crystal structure of the title compound, C(27)H(20)NO(2) (+)·CF(3)SO(3) (-), the cations form inversion dimers through π-π inter-actions between the acridine ring systems [centroid-centroid distances = 3.668 (2)-3.994 (2) Å]. These dimers are further linked by C-H⋯O and C-H⋯π inter-actions. The cation and the anion are connected by C-H⋯O inter-actions. The mean plane of the acridine ring...
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The title compound, C(38)H(26)O(2)·C(6)H(7)N, crystallized as a host-guest complex from a solvent mixture of 4-methyl-pyridine and acetone. The dihedral angle between the rings in the biphenyl unit is 87.06 (3)°. The methyl-pyridine guest mol-ecules are linked to the host mol-ecules via O-H⋯ N hydrogen bonds, forming discrete pairs. The other OH group of the host forms an intra-molecular O-H⋯O ...
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Kinetic studies with 3,4-dihydroxy-9, IO-secoandrosta1,3,5(10)-triene-9,17-dione-4,5-dioxygenase gave intersecting initial velocity plots that conform to a sequential mechanism. Linear noncompetitive product inhibition patterns were observed with respect to either substrate, indicating the formation of a dead end complex. 4-Isopropyl catechol, a structural analogue of the organic substrate, inh...
متن کامل9-(4-Methylphenoxycarbonyl)-10-methylacridinium trifluoromethanesulfonate
In the crystal structure of the title compound, C(22)H(18)NO(2) (+)·CF(3)SO(3) (-), adjacent cations are linked through C-H⋯π and π-π inter-actions, and the cations and anions are connected by C-H⋯O and C-F⋯π inter-actions. The acridine and benzene ring systems are oriented at a dihedral angle of 3.0 (1)°. The carboxyl group is twisted at an angle of 83.1 (1)° relative to the acridine skeleton....
متن کامل9-(4-Chlorophenoxycarbonyl)-10-methylacridinium trifluoromethanesulfonate
In the crystal of the title compound, C(21)H(15)ClNO(2) (+)·CF(3)SO(3) (-), adjacent cations are linked through C-H⋯π and π-π inter-actions [centroid-centroid distance = 3.987 (2) Å], and neighboring cations and anions via C-H⋯O and C-F⋯π inter-actions. The acridine ring system and benzene ring are oriented at a dihedral angle of 1.0 (1)° while the carboxyl group is twisted at an angle of 85.0 ...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2009
ISSN: 1600-5368
DOI: 10.1107/s1600536809007569